Just so on the topic of chemicals in the cistern. It wouldn't be the first cistern to eventually go bad, the reasons for that are varied. You sometimes have to deal with pool chemicals or similar. Of course, you meticulously check the values before sealing it, obviously. So a cistern is neither destroyed by the red wine spilled on the terrace nor by that one drop of window cleaner that sneaked past the vacuum/mop.
I would just consider whether I even want this water from the ACO channel in the cistern. Even if you have absolutely ZERO protection from rain over the channel (which is a stupid idea anyway, because where rain gets, sun also gets, and the last thing I want in summer is an unprotected glass south-facing front), the yield amounts from this channel are quite manageable. If I had such a channel and were allowed to lead it into the sewer, I would do it immediately. We are not allowed to lead rule water into the sewer and I had already built a far-protruding balcony over the terrace doors, so I don't have a channel. No channel, no problem.