Without having detailed information about the concrete walls, without plaster and without guarantee of correct input on the U-value calculator portal, the following example U-values result
(according to the Energy Saving Ordinance, exterior walls facing outside air may have a maximum U-value of 0.28)
24cm concrete: U-value 3.65
24cm concrete + 12cm EPS insulation 035: U-value 0.270
24cm concrete + 14cm EPS insulation 035: U-value 0.233
24cm concrete + 16cm EPS insulation 035: U-value 0.206
24cm concrete + 18cm EPS insulation 035: U-value 0.184
If poorer insulation is chosen (EPS 040 or EPS 045), the U-values are correspondingly higher.
Whether it ever makes economic sense mathematically depends in particular on future electricity costs for heating, I think, since these can also be (significantly? crystal ball!) higher than €0.30/kWh. The insulation costs, on the other hand, are a "one-time expense."
From a purely intuitive point of view, I would choose 16cm insulation.
I also see the economic viability as difficult mathematically. Whether it could ever play a role when selling the house, I rather think not.