If he is already working based on comparative offers, that should be okay, and the first items seem to be correct – I would just warn against calculating purely based on BKI, as nothing sensible came out for us there. Plaster should roughly fit, and painter and screed are not the big items anyway – if it ends up 20% more, it hardly matters. For many other items, it depends on the execution in the end: For parquet, you can take material for 50 euros/sqm, or 300 euros. Interior doors you can get for 300 euros each, but also for 1,500 euros. Similar with tiles, sanitary items, etc.
Windows are a difficult item. First of all, it’s a huge factor whether you choose plastic, wood, or wood-aluminum. With plastic you will definitely manage, with wood-aluminum it would probably be tight I think. You can ask the architect what he has planned there. A huge cost driver are large lift-and-slide doors; one of those can swallow a five-digit amount if you want something fancy.
For conventional electricity, 50,000 euros should be sufficient; for a bit of KNX, reckon 15,000-20,000 on top.
In the end, I think it will be a question of cost discipline for you. For earthworks and shell construction – once the plan is set – there’s little room to save. For all other items, if necessary, there is.