I have no experience with this. Mold develops at around 70%, but there is also a wood fungus or something similar, and I believe this appears already at 50%. You should definitely ventilate the attic properly, that is, with controlled residential ventilation. I would even consult an expert for this (probably doesn’t cost much money...). The gap between the purlin and the ring beam is usually sealed with a silicone-like compound. Tape probably won’t hold well on the concrete floor because of dust. The compound is actually applied during construction in the full or nearly full width under the purlin, not at the corner. The insulation of the roof still seems pointless to me overall; the effective insulation layer should be due to the ventilation from the upper floor? I am not sure.