If you want further explanations on this, you’ll find plenty of information on the web; among others at Chemie.de, the Fraunhofer Institute, or also the University of Bochum. I am not a natural scientist right now,...
And I am a natural scientist and wonder about some things that are unnecessarily complicated on the technical application side.
On the other hand, since there are aerated concrete, Poroton, and KS with different thermal conductivities (depending on bulk density)
You will almost always have a higher thermal conductivity for interior walls than for exterior walls, and the (insulated) exterior wall will almost always have about room temperature on the inside. Therefore, I cannot imagine how condensation could form there. In addition, with Poroton, you usually use a denser clay brick on the inside, with better thermal conductivity. The only construction where one could deliberately cause condensation with an interior wall in butt joint (which is what we are talking about here, I thought) would be if a thick aerated concrete or Poroton wall is butt-joined to a thin uninsulated KS or brick exterior wall. That could possibly happen if someone installs aerated concrete inside a bathroom during an old building renovation.
I can assure you for our work that we always try to avoid mixed masonry; with the prevention of crack formation being the primary concern.
But a dumb question: What about non-load-bearing interior walls? Those can be decoupled, right? And theoretically, lightweight walls are mixed masonry anyway.
Anyone who insists on KS should, in my opinion, do so fully consistently and learn to accept insulated exterior masonry.
Which, in my layman’s opinion, is anyway the most consistent construction method (ideally combined with a ventilated curtain facade, which is of course not quite cheap) since you can best avoid thermal bridges.
Whoever prefers a monolithic wall construction and is sound-sensitive can resort to proven lightweight construction in the attic, which also facilitates later remodeling.
Or at least with Poroton inside one should build with smooth bricks RDK 1.4 or even soundproof bricks RDK 2, and also not skimp on load-bearing walls; unless you want to acoustically share everything from music to sneezing, coughing, and toilet use to lovemaking with all the house residents.
With 36.5 cm exterior masonry – whether aerated concrete, Poroton, pumice, or expanded clay – hopefully we are no longer talking about missing sound insulation.
At least not with exterior masonry in a quiet residential area.
A dumb question I don’t quite understand: Why do people always talk only about mass in sound insulation? Ultimately, it also depends on the damping by the material and the overall structure. Regarding the latter: If, for example, I have a load-bearing ceiling across the entire width of the house, structure-borne sound spreads much better than if I have a load-bearing interior wall. And a very stiff wall transmits sound better than a more damping material; a decoupled double-shell wall much less (can’t you do that at least with lightweight walls, with separated stud frames for both sides?).