Roof windows do not make sense to me for moisture removal. Daylight is, of course, a different matter. For example, you cannot open the roof window in winter and rain or only for a few minutes a day. In summer, the outdoor humidity is often so high that opening it would also be disadvantageous.
Since the controlled residential ventilation system has been in operation, we have kept all windows closed and only opened them for cleaning. Only in the bathroom do we briefly open the window + roof window after my wife has taken a hot shower for 15 minutes. However, the humidity in the bathroom then reaches 90%. By the way, we have never used our clothes dryer since the controlled residential ventilation system has been running. It will be getting thrown out soon.
Of course, good planning of the controlled residential ventilation system is important. Exhaust air should be extracted from rooms where moisture/odor is generated (bathrooms, kitchen, and also a laundry room...). Supply air should be delivered to living and sleeping areas. In our kitchen and main bathroom, we installed double exhaust ducts.