Bridging 40-50m to our property.
Now I wonder if 5x16mm2 is sufficient or if it must be 5x25mm2.
We need 1x63A and 2x32A for the construction.
Now back to your question:
The question cannot be answered with the given information.
I assume that the _construction_ requires 63A and 2x32A connections for the construction site distribution boards.
You don't have to assume that all connections will be loaded with the maximum available power. (The electrical engineer in the above example actually overlooked this.)
The question is rather what will be operated with it. For example, if you have a crane, it will get a 32 A connection alone. However, it usually only rarely draws the nominal current. Namely only when it lifts a heavy concrete bucket or similar and simultaneously swivels and moves. And even then it does not draw 32 A but rather about 25 A.
The same applies to all other plugged-in consumers. Very few are operated at full load permanently.
Now you have to consider what you need on your construction site and have a little courage in your assessment.
Example:
Crane: 25 A (but not permanently)
Screed pump 55 A (only for a certain time on site, but then runs for a longer period)
Several construction dryers with 4 A each = 12 A again permanently
Hand machines, circular saws and other gadgets then add another 5 A.
In total that is 25 A + 55 A + 12 A + 5 A = 97 A, so 100 A
Because all of this never runs at the same time, a maximum load of about 80 A can be assumed. This also covers the extreme case where crane and screed pump run simultaneously.
If the cable is not buried, you will do very well with a 5 x 16 mm² cable. That permanently tolerates 85 A and the crane will not run continuously.
For comparison: 25 mm² with the same laying method can handle about 110 A, but you will not need that at a normal construction site.
In your place, I would lay 2 cables with 5 x 6 mm² each. This is usually cheaper than the 16 mm² cable and can carry 92 A in total.
The friendly and competent electrician will of course help you with the execution.